!################################################################################! ! CCATT-BRAMS/MCGA-CPTEC/WRF emission model CPTEC/INPE ! ! Version 1.8.3: set/2017 ! ! Coded by Saulo Freitas and Karla Longo; updated by Daniela Franca ! ! Contact: brams support: brams_help@cptec.inpe.br - http://brams.cptec.inpe.br ! !################################################################################! module AeM_emission_factors ! ------------------------------------------------ ! Indices for the emission-factors matrix data ! ------------------------------------------------ ! Column - Bioma ! ------------------------------------------------ integer :: & TropFor = 01, & ! TropFor ExtratropF = 02, & ! ExtratropF Savanna = 03, & ! Savanna pasture = 04, & ! pasture/cropland Biofuel = 05, & ! Biofuel CharcMak = 06, & ! CharcMak CharcBurn = 07, & ! CharcBurn AgResid = 08, & ! AgResid Laboratory = 09, & ! Laboratory Molec_Weight = 10, & ! Molec. Weight ! ------------------------------------------------ ! Line - Gas ! ------------------------------------------------ CO2 = 01, & !CO2 CO = 02, & !CO CH4 = 03, & !CH4 NHMC = 04, & !NHMC C2H2 = 05, & !C2H2 C2H4 = 06, & !C2H4 C2H6 = 07, & !C2H6 C3H4 = 08, & !C3H4 C3H6 = 09, & !C3H6 C3H8 = 10, & !C3H8 butene_1 = 11, & !1-butene butene_i = 12, & !i-butene butene_tr_2 = 13, & !tr-2-butene butene_cis_2 = 14, & !cis-2-butene butadiene = 15, & !butadiene butane_n = 16, & !n-butane butane_i = 17, & !i-butane pentene_1 = 18, & !1-pentene pentene_2 = 19, & !2-pentene (cis&trans) pentane_n = 20, & !n-pentane Butene_2_Me = 21, & !2-Me-Butene butane_2_Me = 22, & !2-Me-butane pentadienes = 23, & !pentadienes Isoprene = 24, & !Isoprene cyclopentene = 25, & !cyclopentene cyclopentadiene = 26, & !cyclopentadiene pentene_4_me_1 = 27, & !4-me-1-pentene pentene_2_me_1 = 28, & !2-me-1-pentene hexene_1 = 29, & !1-hexene hexadienes = 30, & !hexadienes hexane_n = 31, & !n-hexane isohexanes = 32, & !isohexanes heptane = 33, & !heptane octenes = 34, & !octenes terpenes = 35, & !terpenes benzene = 36, & !benzene toluene = 37, & !toluene xylenes = 38, & !xylenes ethylbenzene = 39, & !ethylbenzene styrene = 40, & !styrene PAH = 41, & !PAH Methanol = 42, & !Methanol Ethanol = 43, & !Ethanol Propanol_1 = 44, & !1-Propanol propanol_2 = 45, & !2-propanol Butanols = 46, & !Butanols cyclopentanol = 47, & !cyclopentanol phenol = 48, & !phenol Formaldehyde = 49, &!Formaldehyde Acetald = 50, &!Acetald Hydroxyacetaldehyde = 51, &!Hydroxyacetaldehyde Acrolein = 52, &!Acrolein Propanal = 53, & !Propanal Butanals = 54, & !Butanals Hexanals = 55, & !Hexanals Heptanals = 56, & !Heptanals Acetone = 57, & !Acetone Butanone_2 = 58, & !2-Butanone Butanedione_2_3 = 59, & !2,3-Butanedione Pentanones = 60, & !Pentanones Hexanones = 61, & !Hexanones Heptanones = 62, & !Heptanones Octanones = 63, & !Octanones Benzaldehyde = 64, & !Benzaldehyde Furan = 65, & !Furan Me_Furan_2 = 66, & !2-Me-Furan Me_Furan_3 = 67, & !3-Me-Furan ethylfuran_2 = 68, & !2-ethylfuran dime_furan_2_4 = 69, & !2,4-dime-furan Dime_furan_2_5 = 70, & !2,5-Dime-furan Tetrahydrofuran = 71, & !Tetrahydrofuran dihydrofuran_2_3 = 72, & !2,3-dihydrofuran benzofuran = 73, & !benzofuran Furfural = 74, & !Furfural Me_format = 75, & !Me-format Me_Acetate = 76, & !Me-Acetate Acetonitrile = 77, & !Acetonitrile Acrylonitrile = 78, & !Acrylonitrile Propionitrile = 79, & !Propionitrile pyrrole = 80, & !pyrrole trimethylpyrazole = 81, & !trimethylpyrazole methylamine = 82, & !methylamine dimethylamine = 83, & !dimethylamine ethylamine = 84, & !ethylamine trimethylamine = 85, & !trimethylamine n_pentylamine = 86, & !n-pentylamine me_1_butylamine_2 = 87, & !2-me-1-butylamine HFo = 88, & !HFo HAc = 89, & !HAc Propanoic = 90, & !Propanoic acid H2 = 91, & !H2 NOx = 92, & !NOx NOy = 93, & !NOy N2O = 94, & !N2O NH3 = 95, & !NH3 HCN = 96, & !HCN cyanogen = 97, & !cyanogen N2 = 98, & !N2 SO2 = 99, & !SO2 DMS =100, & !DMS COS_ =101, & !COS CH3Cl =102, & !CH3Cl CH3Br =103, & !CH3Br CH3I =104, & !CH3I Hg =105, & !Hg BBURN2 =106, & !PM2.5 BBURN3 =107, & !old - TPM TC =108, & !TC OC =109, & !OC BC =110 !BC !--------------------------------------------------------------------------------------------------- integer, parameter :: AeM_nspecies=110 character(LEN=20),dimension(AeM_nspecies),parameter :: AeM_spc_name= & ! avoid tab character !'12345678901234567890' (/ & 'CO2 '& ,'CO '& ,'CH4 '& ,'NHMC '& ,'C2H2 '& ,'C2H4 '& ,'C2H6 '& ,'C3H4 '& ,'C3H6 '& ,'C3H8 '& ,'1_butene '& ,'i-butene '& ,'tr_2_butene '& ,'cis_2_butene '& ,'butadiene '& ,'n_butane '& ,'i-butane '& ,'1_pentene '& ,'2_pentene '& ,'n_pentane '& ,'2_Me_Butene '& ,'2_Me_butane '& ,'pentadienes '& ,'Isoprene '& ,'cyclopentene '& ,'cyclopentadiene '& ,'4_me_1_pentene '& ,'2_me_1_pentene '& ,'1_hexene '& ,'hexadienes '& ,'n_hexane '& ,'isohexanes '& ,'heptane '& ,'octenes '& ,'terpenes '& ,'benzene '& ,'toluene '& ,'xylenes '& ,'ethylbenzene '& ,'styrene '& ,'PAH '& ,'Methanol '& ,'Ethanol '& ,'1_Propanol '& ,'2_propanol '& ,'Butanols '& ,'cyclopentanol '& ,'phenol '& ,'Formaldehyde '& ,'Acetald '& ,'Hydroxyacetaldehyde '& ,'Acrolein '& ,'Propanal '& ,'Butanals '& ,'Hexanals '& ,'Heptanals '& ,'Acetone '& ,'2_Butanone '& ,'2_3_Butanedione '& ,'Pentanones '& ,'Hexanones '& ,'Heptanones '& ,'Octanones '& ,'Benzaldehyde '& ,'Furan '& ,'2_Me_Furan '& ,'3_Me_Furan '& ,'2_ethylfuran '& ,'2_4_dime_furan '& ,'2_5_Dime_furan '& ,'Tetrahydrofuran '& ,'2_3_dihydrofuran '& ,'benzofuran '& ,'Furfural '& ,'Me_format '& ,'Me_Acetate '& ,'Acetonitrile '& ,'Acrylonitrile '& ,'Propionitrile '& ,'pyrrole '& ,'trimethylpyrazole '& ,'methylamine '& ,'dimethylamine '& ,'ethylamine '& ,'trimethylamine '& ,'n_pentylamine '& ,'2_me_1_butylamine '& ,'HFo '& ,'HAc '& ,'Propanoic '& ,'H2 '& ,'NOx '& ,'NOy '& ,'N2O '& ,'NH3 '& ,'HCN '& ,'cyanogen '& ,'N2 '& ,'SO2 '& ,'DMS '& ,'COS '& ,'CH3Cl '& ,'CH3Br '& ,'CH3I '& ,'Hg '& ,'BBURN2 '& !PM25 ,'BBURN3 '& !PM10 ,'TC '& ,'OC '& ,'BC '& /) !--------------------------------------------------------------------------------------------------- real, dimension(10,AeM_nspecies) :: emission_factor data emission_factor/ & !--------------------------------------------------------------------------------------------------- ! Emission Factor !--------------------------------------------------------------------------------------------------- ! TropFor! Extra !Savanna! pasture | Biofuel! CharcMak ! CharcBurn ! AgResid ! Laboratory ! Molec. ! ! !tropF ! ! cropland| ! ! ! ! ! Weight ! !--------------------------------------------------------------------------------------------------- 1631., 1576., 1643., 1643., 1464., 478., 2573., 1457., 1476., 44.01, & ! CO2 100., 112., 71., 71., 84., 84., 220., 87., 89., 28.01, & ! CO 6.8, 5.1, 2.6, 2.6, 6.6, 12.2, 6.7, 8.2, 4.5, 16.04, & ! CH4 7.1, 8.7, 5.5, 5.5, 7.7, 17.5, 4.6, 9.9, 8.7, 15.00, & ! NHMC 0.433, 0.289, 0.308, 0.308, 0.637, 0.350, 0.245, 0.221, 0.308, 26.04, & ! C2H2 1.109, 1.570, 0.925, 0.925, 1.138, 1.092, 0.583, 1.454, 1.095, 28.05, & ! C2H4 0.943, 0.813, 0.414, 0.414, 0.728, 2.137, 0.655, 1.142, 1.065, 30.07, & ! C2H6 0.013, 0.051, 0.038, 0.038, 0.290, -9999, 0.071, 0.030, -9999, 40.06, & ! C3H4 0.864, 0.699, 0.473, 0.473, 0.649, 1.012, 0.399, 0.700, 0.671, 42.08, & ! C3H6 0.538, 0.310, 0.138, 0.138, 0.281, 0.350, 0.207, 0.258, 0.151, 44.10, & ! C3H8 0.073, 0.125, 0.081, 0.081, 0.171, -9999, 0.113, 0.099, -9999, 56.11, & ! 1-butene 0.109, 0.096, 0.041, 0.041, 0.165, -9999, 0.087, 0.079, 0.410, 56.11, & ! i-butene 0.033, 0.041, 0.022, 0.022, 0.202, -9999, 0.037, 0.041, 0.040, 56.11, &! tr-2-butene 0.031, 0.041, 0.018, 0.018, 0.110, -9999, 0.023, 0.031, 0.026, 56.11, &! cis-2-butene 0.094, 0.111, 0.091, 0.091, 0.168, -9999, 0.062, 0.085, 0.136, 54.09, &! butadiene 0.041, 0.094, 0.023, 0.023, 0.038, -9999, 0.066, 0.039, 0.040, 58.12, &! n-butane 0.015, 0.036, 0.009, 0.009, 0.047, -9999, 0.010, 0.015, -9999, 58.12, &! i-butane 0.058, 0.042, 0.030, 0.030, 0.135, -9999, 0.028, 0.005, 0.011, 70.13, &! 1-pentene 0.012, 0.030, 0.021, 0.021, 0.008, -9999, 0.023, 0.030, 0.014, 70.13, &! 2-pentene (cis&trans) 0.014, 0.044, 0.008, 0.008, 0.020, -9999, 0.096, 0.085, 0.030, 72.15, &! n-pentane 0.076, 0.077, 0.028, 0.028, 0.096, -9999, 0.015, 0.016, 0.013, 70.13, &! 2-Me-Butene 0.008, 0.027, 0.009, 0.009, 0.041, -9999, 0.071, 0.007, 0.004, 72.15, &! 2-Me-butane -9999, 0.024, 0.048, 0.048, 0.019, -9999, -9999, -9999, 0.024, -9999, &! pentadienes 0.218, 0.107, 0.044, 0.044, 0.099, -9999, 0.017, 0.401, 0.044, 68.12, &! Isoprene 0.019, 0.041, 0.024, 0.024, 0.308, -9999, 0.035, 0.016, 0.006, 68.12, &! cyclopentene 0.027, 0.027, 0.026, 0.026, 0.061, -9999, 0.052, 0.001, 0.023, 66.11, &! cyclopentadiene 0.049, 0.052, 0.049, 0.049, 0.015, -9999, 0.098, 0.015, -9999, 84.16, &! 4-me-1-pentene -9999, 0.072, 0.042, 0.042, -9999, -9999, -9999, -9999, -9999, 84.16, &! 2-me-1-pentene 0.066, 0.086, 0.047, 0.047, 0.020, -9999, 0.141, 0.012, 0.026, 84.16, &! 1-hexene -9999, -9999, 0.006, 0.006, -9999, -9999, -9999, -9999, 0.065, -9999, &! hexadienes 0.048, 0.043, 0.018, 0.018, 0.008, -9999, 0.063, 0.005, 0.007, 86.17, &! n-hexane 0.076, 0.042, 0.016, 0.016, 0.161, -9999, 0.149, 0.240, -9999, 86.17, &! isohexanes 0.032, 0.035, 0.056, 0.056, 0.006, -9999, 0.063, 0.070, -9999, 98.17, &! heptane 0.012, 0.031, 0.021, 0.021, 0.007, -9999, 0.017, 0.003, 0.018, 112.22,&! octenes 0.150, 2.003, 0.138, 0.138, 0.114, -9999, 0.000, 0.005, 1.400, 136.24,&! terpenes 0.379, 0.476, 0.324, 0.324, 0.878, -9999, 1.124, 0.387, 0.355, 78.11, &! benzene 0.235, 0.319, 0.181, 0.181, 0.494, -9999, 0.380, 0.195, 0.319, 90.10, &! toluene 0.087, 0.177, 0.086, 0.086, 0.234, -9999, 0.148, 0.114, 0.087, 106.17,&! xylenes 0.043, 0.044, 0.024, 0.024, 0.124, -9999, 0.048, 0.067, 0.026, 106.17,&! ethylbenzene 0.028, 0.066, 0.061, 0.061, 0.224, -9999, 0.133, 0.028, 0.018, 104.15,&! styrene 0.100, 0.019, 0.0187, 0.0187, 0.151, -9999, 0.025, 0.069, 0.0640, -9999, &! PAH 3.149, 2.073, 1.417, 1.417, 3.493, 12.300, 1.240, 2.810, 1.359, 32.04, &! Methanol 0.017, 0.053, 0.217, 0.217, 0.013, -9999, 0.033, 0.014, 0.097, 46.07, &! Ethanol 0.041, 0.042, 0.025, 0.025, 0.030, -9999, 0.080, 0.034, 0.248, 60.10, &! 1-Propanol -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, 0.210, -9999, &! 2-propanol 0.009, 0.012, 0.108, 0.108, 0.051, -9999, 0.022, 0.011, 0.025, 74.12, &! Butanols 0.032, 0.044, 0.033, 0.033, 0.032, -9999, 0.084, 0.016, -9999, 86.13, &! cyclopentanol 0.228, 0.252, 0.427, 0.427, 0.932, 2.750, 1.659, 0.585, 1.912, 94.11, &! phenol 2.400, 2.144, 1.215, 1.215, 0.864, 1.060, 0.733, 1.811, 1.590, 30.03, &! Formaldehyde 2.260, 1.072, 0.564, 0.564, 0.362, -9999, 1.278, 1.448, 0.831, 45.06, &! Acetald 0.961, 0.390, 0.250, 0.250, 0.660, -9999, 0.961, 0.961, 0.961, 60.05, &! Hydroxyacetaldehyde 0.650, 0.349, 0.384, 0.384, 0.052, -9999, 0.347, 1.160, 0.372, 56.06, &! Acrolein 0.100, 0.122, 0.068, 0.068, 0.072, -9999, 0.145, 0.180, 0.545, 58.08, &! Propanal 0.127, 0.141, 0.114, 0.114, 0.030, -9999, 0.202, 0.170, 0.021, 72.11, &! Butanals 0.021, 0.055, 0.048, 0.048, 0.063, -9999, 0.091, 0.020, 0.003, 102.17,&! Hexanals 0.004, 0.004, 0.003, 0.003, 0.374, -9999, 0.008, 0.001, 0.004, 114.19,&! Heptanals 0.630, 0.655, 0.441, 0.441, 0.324, 0.175, 1.355, 1.130, 0.726, 64.13, &! Acetone 0.500, 0.231, 0.146, 0.146, 0.084, -9999, 0.832, 0.900, 0.285, 72.11, &! 2-Butanone 0.730, 0.764, 0.268, 0.268, 0.013, -9999, 1.750, 1.310, 1.033, 86.08, &! 2,3-Butanedione 0.059, 0.054, 0.015, 0.015, 0.029, -9999, 0.092, 0.104, 0.038, 86.13, &! Pentanones -9999, -9999, 0.048, 0.048, -9999, -9999, -9999, -9999, 0.007, -9999, &! Hexanones 0.002, 0.006, 0.006, 0.006, 0.004, -9999, 0.011, 0.002, 0.117, 114.19,&! Heptanones 0.020, 0.023, 0.015, 0.015, 0.016, -9999, 0.043, 0.018, 0.005, 128.22,&! Octanones 0.028, 0.132, 0.172, 0.172, 0.034, -9999, 0.070, 0.008, 0.058, 106.12,&! Benzaldehyde 0.330, 0.471, 0.284, 0.284, 0.414, 1.150, 0.863, 1.030, 0.934, 68.08, &! Furan 0.278, 0.337, 0.166, 0.166, 0.177, -9999, 0.460, 0.531, 0.550, 82.10, &! 2-Me-Furan 0.055, 0.034, 0.011, 0.011, 0.013, -9999, 0.061, 0.076, 0.063, 82.10, &! 3-Me-Furan 0.003, 0.016, 0.007, 0.007, 0.003, -9999, 0.007, 0.001, -9999, 94.10, &! 2-ethylfuran 0.024, 0.019, 0.008, 0.008, 0.003, -9999, 0.037, 0.002, -9999, 96.13, &! 2,4-dime-furan 0.028, 0.070, 0.015, 0.015, 0.035, -9999, 0.054, 0.023, 0.289, 96.13, &! 2,5-Dime-furan 0.017, 0.001, 0.007, 0.007, 0.016, -9999, 0.042, 0.006, 0.002, 72.12, &! Tetrahydrofuran 0.014, 0.018, 0.014, 0.014, 0.013, -9999, 0.033, 0.005, -9999, 70.10, &! 2,3-dihydrofuran 0.016, 0.094, 0.073, 0.073, 0.016, -9999, 0.042, 0.004, 0.014, 118.14,&! benzofuran 0.384, 0.616, 0.290, 0.290, 0.129, 1.049, 0.749, 0.315, 2.054, 96.09, &! Furfural 0.024, 0.024, 0.073, 0.073, 0.018, -9999, 0.047, 0.020, 0.043, 60.05, &! Me-format 0.095, 0.094, 0.193, 0.193, 0.105, -9999, 0.186, 0.078, 0.112, 74.05, &! Me-Acetate 0.478, 0.230, 0.182, 0.182, 0.179, -9999, 0.180, 0.283, 0.173, 41.05, &! Acetonitrile 0.040, 0.034, 0.034, 0.034, 0.030, -9999, 0.000, 0.080, 0.040, 53.10, &! Acrylonitrile 0.090, -9999., 0.012, 0.012, -9999., -9999, 0.000, 0.170, 0.020, 55.07, &! Propionitrile 0.120, 0.012, 0.013, 0.013, -9999., -9999, 0.000, 0.220, 0.017, 67.09, &! pyrrole -9999., -9999., -9999., -9999., -9999., -9999, 0.000, -9999., 0.124, 110.16,&! trimethylpyrazole -9999., -9999., -9999., -9999., -9999., -9999, 0.000, -9999., 0.057, 31.06, &! methylamine -9999., -9999., -9999., -9999., -9999., -9999, 0.000, -9999., 0.062, 45.09, &! dimethylamine -9999., -9999., -9999., -9999., -9999., -9999, 0.000, -9999., 0.010, 45.09, &! ethylamine -9999., -9999., -9999., -9999., -9999., -9999, 0.000, -9999., 0.041, 59.11, &! trimethylamine -9999., -9999., -9999., -9999., -9999., -9999, 0.000, -9999., 0.439, 87.17, &! n-pentylamine -9999., -9999., -9999., -9999., -9999., -9999, 0.000, -9999., 0.140, 87.17, &! 2-me-1-butylamine 0.988, 1.545, 0.23, 0.23, 0.409, 0.450, 0.119, 0.883, 0.770, 47.02, &! HFo 3.283, 3.369, 2.01, 2.01, 11.96, 8.920, 1.845, 4.649, 2.813, 60.05, &! HAc -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, 0.560, -9999, &! Propanoic acid 3.07, 1.80, 0.97, 0.97, 1.762, -9999, 4.670, 2.65, -9999., 2.02, &! H2 2.55, 2.77, 2.27, 2.27, 1.74, 0.05, 2.32, 2.19, 1.87, 30.01, &! NOx -9999., 0.67, 2.20, 2.20, -9999., 0.00, 0.00, -9999., 0.00, 0.00, &! NOy 0.20, 0.25, 0.19, 0.19, 0.13, 0.02, 0.35, 0.10, 0.06, 44.01, &! N2O 1.45, 1.31, 0.97, 0.97, 1.60, 0.23, 0.80, 1.37, 1.61, 18.02, &! NH3 0.38, 0.77, 0.38, 0.38, 0.30, 0.30, 0.30, 0.40, 0.47, 27.02, &! HCN 0.00, -9999., 0.00, 0.00, -9999., 0.00, 0.00, -9999., 0.01, 52.04, &! cyanogen 2.64, 2.64, 2.64, 2.64, 2.64, -9999, 2.64, 2.64, 4.13, 28.01, &! N2 0.75, 1.36, 0.43, 0.43, 0.29, 0.00, 0.05, 0.50, 0.87, 64.06, &! SO2 0.0022, 0.0141, 0.0011, 0.0011, 0.100, -9999, -9999, -9999, -9999, 0.00, &! DMS 0.025, 0.045, 0.014, 0.014, 0.040, 0.040, 0.040, 0.060, 0.032, 60.07, &! COS 0.075, 0.040, 0.069, 0.069, 0.039, 0.010, 0.012, 0.233, 0.158, 50.49, &! CH3Cl 0.0078, 0.0029, 0.0033, 0.0033, 0.0030, 0.0030, 0.0030, 0.0030, 0.0008, 94.94, &! CH3Br 0.0068, 0.0005, 0.0008, 0.0008, 0.0010, -9999, 0.0010, 0.0010, -9999., 141.94,&! CH3I 5.E-05, 1.3E-04, 1.1E-04, 1.1E-04, 6.8E-06, 0.E-05, 5.E-05, 3.7E-05, 3.7E-5, 200.59,&! Hg 8.3, 15.7, 7.5, 7.5, 6.0, 2.1, 1.6, 7.4, 5.1, -9999, &! PM2.5 11.8, 17.6, 8.2, 8.2, 6.9, 4.3, 2.4, 10.8, 7.2, -9999, &! PM10 (old TPM) 6.0, 8.3, 4.0, 4.0, 3.4, -9999, 3.3, 4.4, 3.6, 12.00, &! TC 4.3, 7.7, 3.3, 3.3, 3.1, -9999, 4.8, 4.0, 2.5, 12.00, &! OC 0.56, 0.58, 0.61, 0.61, 0.54, -9999, 1.50, 0.41, 1.08, 12.00 / ! BC !index_bioma =2 !index_gas=2 !print*, emission_factor(index_bioma, index_gas) !print*,spc_name(index_gas) end module AeM_emission_factors